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"en": "Abstract. To provide a tool for fast estimation of the Fe3+content in Ca2(Al, Fe3+)3Si3O12(OH) epidote grains,including in thin sections and crude-rock samples, we applied Ramanspectroscopy to 33 areas from 15 natural samples with Fe3+ ranging from0.22 to 1.13 atoms per formula unit (apfu), the chemistry of which wasindependently determined by wavelength-dispersive electron microprobeanalysis (WD-EPMA). The Raman spectra were collected from the very areassubjected to WD-EPMA. We have analysed both the OH-stretching region(3215–3615 cm−1) and the spectral range generated by the frameworkvibrations (15–1215 cm−1). Similarly to the IR spectra, the Raman peaksin the OH-stretching region shift toward higher wavenumbers with increasingFe. However, the quantification of Fe3+ based on OH-stretching Ramanpeaks can be hindered by the multicomponent overlapping and significantintensity variations with the crystal orientation. Among the Raman signalsgenerated by framework vibrations, the position of four peaks (near 250,570, 600, and 1090 cm−1) exhibit a steady linear regression with theincrease in Fe content (in apfu). However, the peak near 250 cm−1attributed to MO6 vibrations also depends on the crystal orientationand therefore is not always well resolved, which worsens the accuracy inFe-content determination based on its position. The peaks near 570, 600, and1090 cm−1 arise from Si2O7 vibrational modes, and althoughtheir intensities also vary with the crystal orientation, all three signalsare well resolved in a random orientation. However, among the threeSi2O7-related signals, the 570 cm−1 peak is the sharpest(peak width <10 cm−1) and is easily recognized as a separatepeak. Hence, we propose to use the position of this peak as a highlyreliable parameter to estimate the Fe content, via the linear trend given asω570=577.1(3)-12.7(4)x, where ω is the wavenumber(cm−1) and x is Fe content (apfu), with accuracy ± 0.04Fe3+ apfu. The peaks near 600 and 1090 cm−1 may be complementarilyused for the Fe estimate, based on the following relations: ω600=611.6(2)-13.8(4)x and ω1090=1098.8(3)-13.5(5)x. Analyses ofthe effect of Sr as a substitution for Ca and Cr at the octahedral sitesindicate that contents of Sr <0.12 apfu do not interfere with thequantification of Fe via the ω570 (x) relation, whereas Cr>0.16 apfu leads to overestimation of Fe; Cr presence can berecognized however by the broadening of the peaks near 95 and 250 cm−1."
},
"publisher": {
"en": "Copernicus GmbH"
},
"publication_date": "2023-04-06",
"publication_name": {
"en": "European Journal of Mineralogy"
},
"volume": "35",
"number": "2",
"starting_page": "267",
"ending_page": "283",
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"eng"
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"10.5194/ejm-35-267-2023"
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"paper_title": {
"ja": "山口県中部に位置する銀鉱床 ~青景銀山と杉山銀山について~",
"en": "Silver deposits in the middle of Yamaguchi Prefecture: The Aokage and Sugiyama silver deposits"
},
"authors": {
"ja": [
{
"name": "窪津優花"
},
{
"name": "永嶌真理子"
}
],
"en": [
{
"name": "Yuka Kubotsu"
},
{
"name": "Mariko Nagashima"
}
]
},
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"last"
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"publisher": {
"ja": "秋吉台科学博物館"
},
"publication_date": "2023-03",
"publication_name": {
"ja": "秋吉台科学博物館報告",
"en": "Bulletin of the Akiyoshi-dai Museum of Natural History"
},
"volume": "58",
"starting_page": "17",
"ending_page": "32",
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"jpn"
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"paper_title": {
"ja": "史跡周防鋳銭司跡などから出土した資料の鉛同位体比分析."
},
"authors": {
"ja": [
{
"name": "齋藤努"
},
{
"name": "青島啓"
},
{
"name": "齊藤大輔"
},
{
"name": "森福洋二"
},
{
"name": "永嶌真理子"
},
{
"name": "今岡照喜"
},
{
"name": "田中晋作"
}
]
},
"publisher": {
"ja": "国立歴史民俗博物館"
},
"publication_date": "2023-03",
"publication_name": {
"ja": "国立歴史民俗博物館研究報告"
},
"volume": "238",
"starting_page": "59",
"ending_page": "78",
"languages": [
"jpn"
],
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"paper_title": {
"ja": "史跡周防鋳銭司跡出土遺物の産地推定と長登鉱山の特異性.-山口県内の白亜紀鉱山試料の鉛同位体-"
},
"authors": {
"ja": [
{
"name": "今岡照喜"
},
{
"name": "齋藤努"
},
{
"name": "永嶌真理子"
},
{
"name": "田中晋作"
}
]
},
"publisher": {
"ja": "国立歴史民俗博物館"
},
"publication_date": "2023-03",
"publication_name": {
"ja": "国立歴史民俗博物館研究報告"
},
"volume": "238",
"starting_page": "11",
"ending_page": "27",
"languages": [
"jpn"
],
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},
{
"@id": "https://api.researchmap.jp/piemon/published_papers/40818281",
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"paper_title": {
"ja": "山口県長登銅山の鉱化作用に関係した花の山プルトンのU-Pbジルコン年代",
"en": "U-Pb zircon age of the Hanano-yama pluton related to the mineralization in the Naganobori mine, Yamaguchi Prefecture, Japan"
},
"authors": {
"ja": [
{
"name": "今岡照喜"
},
{
"name": "早坂康隆"
},
{
"name": "永嶌真理子"
},
{
"name": "曽根原崇文"
},
{
"name": "宮内真奈"
}
],
"en": [
{
"name": "Imaoka, T"
},
{
"name": "Hayasaka, Y"
},
{
"name": "Nagashima, M"
},
{
"name": "Sonehara, T"
},
{
"name": "Miyauchi, M"
}
]
},
"publisher": {
"ja": "蒜山地質年代学研究所"
},
"publication_date": "2022-12",
"publication_name": {
"ja": "地質技術",
"en": "Engineering Geology of Japan."
},
"volume": "12",
"starting_page": "5",
"ending_page": "17",
"languages": [
"eng"
],
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{
"@id": "https://api.researchmap.jp/piemon/published_papers/40216549",
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"rm:modified": "2022-10-10T07:06:41Z",
"paper_title": {
"ja": "Ferro-ferri-holmquistite, □Li2(Fe2+3Fe3+2)Si8O22(OH)2, Fe2+Fe3+ analogue of holmquistite, from the Iwagi islet, Ehime, Japan",
"en": "Ferro-ferri-holmquistite, □Li2(Fe2+3Fe3+2)Si8O22(OH)2, Fe2+Fe3+ analogue of holmquistite, from the Iwagi islet, Ehime, Japan"
},
"authors": {
"ja": [
{
"name": "Mariko Nagashima"
},
{
"name": "Teruyoshi Imaoka"
},
{
"name": "Takashi Kano"
},
{
"name": "Jun-ichi Kimura"
},
{
"name": "Qing Chang"
},
{
"name": "Takashi Matsumoto"
}
],
"en": [
{
"name": "Mariko Nagashima"
},
{
"name": "Teruyoshi Imaoka"
},
{
"name": "Takashi Kano"
},
{
"name": "Jun-ichi Kimura"
},
{
"name": "Qing Chang"
},
{
"name": "Takashi Matsumoto"
}
]
},
"published_paper_owner_roles": [
"lead",
"corresponding"
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"description": {
"en": "Abstract. Ferro-ferri-holmquistite (IMA2022-020), ideal formula□Li2(Fe32+Fe23+)Si8O22(OH)2, wasfound in albitized granite from the Iwagi islet, Ehime, Japan.Ferro-ferri-holmquistite is a CFe2+Fe3+ analogue ofholmquistite and belongs to the lithium-subgroup amphiboles. It commonlyoccurs as acicular aggregate and/or isolated crystals in quartz, albite andK-feldspar and is blue with a bluish-grey streak and a vitreous luster. Ithas a Mohs hardness of 5 1/2. Its cleavage is perfect on{210}. Measured and calculated densities areDmeas.=3.2 g cm−3 and Dcalc.=3.317 g cm−3,respectively. Ferro-ferri-holmquistite is optically biaxial (-), withα=1.685, β=1.713 and γ=1.727, and ispleochroic, with X= pale blue ∼ pale yellowish blue, Y= deep blue ∼ brownish blue and Z= deep blue ∼ deep bluish violet; X>Z>Y. The magneticsusceptibility is similar to the associated biotite.Ferro-ferri-holmquistite is insoluble in HCl, HNO3 and H2SO4.The empirical formula calculated on the basis of Σ(C+T) = 13 on the results obtained by electronmicroprobe analyzer (EPMA), and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) isA(K0.01Na0.06)Σ0.07B(Li1.95Na0.04Ca0.01)Σ2.00C(Fe2.822+Fe1.393+Al0.51Mg0.22Mn0.052+Ti0.01)Σ5.00T(Si7.98Al0.02)Σ8.00O22(OH)1.94F0.06. Structure refinement convergedto R1= 4.22 %. The space group is orthorhombic Pnma, and theunit-cell parameters are a= 18.5437(2) Å, b= 17.9222(1) Å, c= 5.3123(1) Å and V= 1765.51(1) Å3. Based on the refinedsite occupancies, the structural formula can be written asANa0.062M4(Li1.952Na0.048)Σ2.000M1(Fe1.7702+Mg0.230)Σ2.000M2(Fe1.4463+Fe0.1022+Al0.452)Σ2.000M3(Fe0.8912+Mg0.109)Σ1.000TSi8O22(OH)2 (Z= 4). Three OH-stretching IRbands, centered at 3614, 3631 and 3644 cm−1, are assigned to the localconfiguration M1M1M3= FeFeFe, MgFeFe (including FeMgFe and FeFeMg) andMgMgFe (including MgFeMg and FeMgMg), respectively, based on the IR studiesof the orthorhombic Pnma amphiboles."
},
"publisher": {
"en": "Copernicus GmbH"
},
"publication_date": "2022-10-07",
"publication_name": {
"ja": "European Journal of Mineralogy",
"en": "European Journal of Mineralogy"
},
"volume": "34",
"number": "5",
"starting_page": "425",
"ending_page": "438",
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"eng"
],
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"10.5194/ejm-34-425-2022"
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"paper_title": {
"en": "Role of lone-pair electron localization in temperature-induced phase transitions in mimetite"
},
"authors": {
"en": [
{
"name": "Georgia Cametti"
},
{
"name": "Mariko Nagashima"
},
{
"name": "Sergey V. Churakov"
}
]
},
"description": {
"en": "The crystal structure of mimetite Pb5(AsO4)3Cl, a phosphate with apatite structure-type has been investigated in situ at 123, 173, 273, 288, 353 and 393 K. A careful inspection of the diffraction pattern and subsequent structure refinements indicated that mimetite transforms from the monoclinic to the hexagonal polymorph with increasing temperature. At 123 K, a monoclinic superstructure, mimetite-2M, with cell parameters a = 20.4487 (9), b = 7.4362 (2), c = 20.4513 (9) Å, β = 119.953 (6)°, V = 2694.5 (2) Å3 and space group P21 was observed. From 173 to 353 K, the reflections of the supercell were evident only along one direction of the corresponding hexagonal apatite-cell and the structure transforms to the polymorph mimetite-M with space group P21/b and unit-cell parameters a = 10.2378 (3), b = 20.4573 (7), c = 7.4457 (2) Å, β = 120.039 (5)°, V = 1349.96 (9) Å3. Only at higher temperature, i.e. 393 K, does mimetite adopt the hexagonal space group P63/m characteristic of apatite structure-types. The role of the electron lone pairs of Pb atoms in the phase transition was investigated through the analysis of the electron localization function (ELF) calculated based on the DFT-geometry optimized structures of the three polymorphs. The changes in spatial distribution of the 6s2 electron density during the phase transitions were explored by means of the Wannier Function Centres (WFCs) derived from ab initio molecular dynamics trajectories. In the high-temperature hexagonal structure the 6s2 electrons are spherically symmetric relative to the position of Pb atoms. At low temperature the maximum of 6s2 electron density is displaced relative to the position of Pb atom contributing to the polar interaction in the monoclinic polymorphs."
},
"publisher": {
"en": "International Union of Crystallography (IUCr)"
},
"publication_date": "2022-08-01",
"publication_name": {
"en": "Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials"
},
"volume": "78",
"number": "4",
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"eng"
],
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"doi": [
"10.1107/s2052520622006254"
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"2052-5206"
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"paper_title": {
"en": "Magmatic Processes of the Upper Cretaceous Susuma–Nagaho Plutonic Complex, Southwest Japan: Its Role on Crustal Growth and Recycling in Active Continental Margins"
},
"authors": {
"en": [
{
"name": "Shogo Kodama"
},
{
"name": "Masaaki Owada"
},
{
"name": "Mariko Nagashima"
},
{
"name": "Atsushi Kamei"
}
]
},
"description": {
"en": "Magmatic processes in the active continental margins are one of the important issues to understand the evolution of the continental crust. The Cretaceous Susuma–Nagaho plutonic complex, southwest Japan, is situated at the continental arc, and made up of gabbro, quartz diorite to granodiorite, and granite. According to the field occurrence, they are coeval intrusive rocks, and the biotite K–Ar ages of the granodiorite and granite are approximately 93 Ma, corresponding to the period of a magmatic flare-up in southwest Japan. Based on the whole-rock chemical analyses including Sr–Nd isotopic compositions, the granodiorite magma has been formed through fractional crystallization of basaltic magmas, whereas the origin of granite magma involved partial melting of the continental crust. The gabbro contains calcium-rich plagioclase (An > 90) and the presence of early crystallized hornblende, indicating its derivation from a hydrous basaltic magma. Such basaltic magma intruded into the middle to lower crust and supplied the heat energy necessary for crustal partial melting and granitic magma formation. The fractional crystallization and crustal melting took place at the same time, playing an important role in the crustal growth and differentiation during the magmatic flare-up event."
},
"publisher": {
"en": "MDPI AG"
},
"publication_date": "2022-06-15",
"publication_name": {
"en": "Minerals"
},
"volume": "12",
"number": "6",
"starting_page": "762",
"ending_page": "762",
"languages": [
"eng"
],
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"identifiers": {
"doi": [
"10.3390/min12060762"
],
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"2075-163X"
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"paper_title": {
"ja": "交代性アルビタイトに産するリチウム鉱物の産状・結晶化学・成因 ─岩城島産の村上石を中心として─",
"en": "Mode of Occurrence, Crystal Chemistry, and Origins of Li Minerals of Metasomatic Albitite: Murakamiite from Iwagi Islet, SW Japan"
},
"authors": {
"ja": [
{
"name": "今岡 照喜"
},
{
"name": "永嶌 真理子"
}
],
"en": [
{
"name": "Teruyoshi IMAOKA"
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{
"name": "Mariko NAGASHIMA"
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},
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"ja": "地学雑誌",
"en": "Journal of Geography (Chigaku Zasshi)"
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"number": "2",
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"ending_page": "256",
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"paper_title": {
"en": "The role of scandium substitution in babingtonite group minerals.",
"ja": "The role of scandium substitution in babingtonite group minerals."
},
"authors": {
"en": [
{
"name": "Nagashima, M"
},
{
"name": "Nishio-Hamane, D"
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{
"name": "Matsumoto, T"
},
{
"name": "Fukuda, C"
}
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{
"name": "Nagashima, M"
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{
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{
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"en": "Sc-rich babingtonite from Heftetjern, Norway and Baveno, Italy were examined using electron microprobe analysis and X-ray single-crystal refinement in order to re-examine the behavior of Sc3+ and analyze its effect on the crystal structure of babingtonite. The Sc2O3 content is 13.78 wt.% in the Heftetjern specimen, and 8.44 wt.% in the Baveno one. In contrast, the latter has higher Fe content (11.13 wt.% as FeO) rather than the former one (8.63 wt.% as FeO). Characteristically, both specimens contain sodium. Although the oxidation state of octahedral cations in babingtonites is in general Me2+:Me3+ = 1:1, trivalent cations in the Heftetjern specimen attain 1.14 apfu. This excess of trivalent cations must be counterbalanced by monovalent Na substituted for Ca. The unit-cell parameters are a = 7.5272(1), b = 11.7175(1), c = 6.7613(1) angstrom, alpha = 91.710(1), beta = 93.637(1), gamma = 104.522(1)degrees, and V = 575.49(2) angstrom(3) for the Heftetjern specimen, and a = 7.5199(2), b = 11.7145(3), c = 6.7408(2) angstrom, alpha = 91.756(2), beta = 93.786(2), gamma = 104.549(2)degrees, and V = 573.83(3) angstrom(3) for the Baveno one. The structural formulae are Ca-A1(1.00)A2(Ca0.879Na0.121)(M1)(Sc0.423+Fe0.372+Mn0.212+)(M2)(Sc0.683+Fe0.272+Mg0.03Fe0.023+)Si5O14(OH) for Heftetjern, and Ca-A1(1.00)A2(Ca0.819Na0.181)(M1)(Sc0.433+Mn0.362+Fe0.212+)(M2)(Fe0.363+Fe0.302+Sc0.263+Sn0.054+Al0.03)Si5O14(OH) for Baveno. Due to Sc3+ substitution, the distance, 2.09-2.11 angstrom, is longer than that of Sc-free babingtonite, 2.03-2.05 angstrom. The M2O(6) expansion leads to the lengthened O4-O10 edge shared between the M1O(6) and M2O(6) octahedra, and causes the stronger angular distortion of M2O(6). This can be explained by the increase of the O4-M1-O10 angle and decrease of the O4-M1-O8 angle with lengthening of the O4-O10 edge."
},
"publisher": {
"en": "MDPI"
},
"publication_date": "2022-03",
"publication_name": {
"en": "Minerals",
"ja": "Minerals"
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"number": "3",
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"doi": [
"10.3390/min12030333"
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"paper_title": {
"en": "On the nature of Pb species in Pb-exchanged zeolite stellerite (STI): A combined experimental and theoretical study"
},
"authors": {
"en": [
{
"name": "Diana P. Roos"
},
{
"name": "Andreas C. Scheinost"
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{
"name": "Sergey V. Churakov"
},
{
"name": "Mariko Nagashima"
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{
"name": "Georgia Cametti"
}
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"en": "Elsevier BV"
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"publication_date": "2021-11",
"publication_name": {
"en": "Microporous and Mesoporous Materials"
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"volume": "327",
"starting_page": "111444",
"ending_page": "111444",
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"10.1016/j.micromeso.2021.111444"
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"1387-1811"
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"@id": "https://doi.org/10.1016/j.micromeso.2021.111444",
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"paper_title": {
"ja": "岩城島産エジリンアルビタイト中のデーリー石とゼッツェル石",
"en": "Dalyite (K2ZrSi6O15) and Zektzerite (LiNaZrSi6O15) in Aegirine-bearing Albitite from Iwagi Islet, SW Japan"
},
"authors": {
"ja": [
{
"name": "今岡 照喜"
},
{
"name": "秋田 幸穂"
},
{
"name": "永嶌 真理子"
}
],
"en": [
{
"name": "Teruyoshi IMAOKA"
},
{
"name": "Sachiho AKITA"
},
{
"name": "Mariko NAGASHIMA"
}
]
},
"publisher": {
"en": "Tokyo Geographical Society"
},
"publication_date": "2021-06-25",
"publication_name": {
"ja": "地学雑誌",
"en": "Journal of Geography (Chigaku Zasshi)"
},
"volume": "130",
"number": "3",
"starting_page": "369",
"ending_page": "378",
"languages": [
"eng"
],
"referee": true,
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"doi": [
"10.5026/jgeography.130.369"
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"0022-135X"
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"1884-0884"
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"paper_title": {
"en": "Ore and skarn mineralogy of the Eboshi deposit of the Naganobori copper mine, Yamaguchi, Japan"
},
"authors": {
"en": [
{
"name": "Mariko NAGASHIMA"
},
{
"name": "Yukina MORISHITA"
},
{
"name": "Yuji IMOTO"
},
{
"name": "Teruyoshi IMAOKA"
}
]
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"en": "Japan Association of Mineralogical Sciences"
},
"publication_date": "2021-02",
"publication_name": {
"en": "Journal of Mineralogical and Petrological Sciences"
},
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"eng"
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"doi": [
"10.2465/jmps.200818"
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"paper_title": {
"en": "Chemical and lithium isotope characteristics of murakamiite and Li–rich pectolite from Iwagi Islet, Southwest Japan"
},
"authors": {
"en": [
{
"name": "Teruyoshi IMAOKA"
},
{
"name": "Jun–Ichi KIMURA"
},
{
"name": "Qing CHANG"
},
{
"name": "Tsuyoshi ISHIKAWA"
},
{
"name": "Mariko NAGASHIMA"
},
{
"name": "Natsuki TAKESHITA"
}
]
},
"publisher": {
"en": "Japan Association of Mineralogical Sciences"
},
"publication_date": "2021-02",
"publication_name": {
"en": "Journal of Mineralogical and Petrological Sciences"
},
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"eng"
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"doi": [
"10.2465/jmps.200721"
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"paper_title": {
"en": "Ferriprehnite, Ca2Fe3+(AlSi3)O10(OH)2, an Fe3+ analogue of prehnite, from Kouragahana, Shimane Peninsula, Japan"
},
"authors": {
"en": [
{
"name": "Mariko NAGASHIMA"
},
{
"name": "Daisuke NISHIO–HAMANE"
},
{
"name": "Shuichi ITO"
},
{
"name": "Takahiro TANAKA"
}
]
},
"published_paper_owner_roles": [
"lead"
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"description": {
"en": "Ferriprehnite (IMA2020 -057), ideal formula Ca2Fe3+(AlSi3)O-10(OH)(2), is a new mineral that was found as secondary mineral in druses developed in the hydrothermal altered dolerite from Kouragahana, Shimane Peninsula, Japan. Ferriprehnite is an Fe analogue of prehnite. The crystals consisting of ferriprehnite and prehnite occur as a radial aggregate. The tabular crystals are up to 300 mu m long, 100 mu m wide, and 50 mu m thick. Ferriprehnite is colorless to pale green with white streak and vitreous luster. It has a Mohs hardness of 6 1/2. Its cleavage is good on {100}. The calculated density is 2.97 g/cm(3). The empirical formula of ferriprehnite on the basis of 10O + 2OH using the result obtained by electron microprobe analysis is Ca-1.99(Fe0.663+Al0.34)(Sigma 1.00)(Al1.02Si2.98)(Sigma 4.00)O-10(OH)(2). Structure refinement converged to R1 = 4.64%. Its space group is orthorhombic Pma2 with unit -cell parameters a = 18.6149(10) angstrom, b = 5.4882(3) angstrom, c = 4.6735(3) angstrom, and V = 477.46(1) angstrom(3). The determined site occupancy at the octahedral M site is Fe0.637(9)Al0.363 indicating that the M site is predominantly occupied by Fe. < M-O > increases with increasing Fe content leading to isotropic expansion of MO6 octahedra. The a- and c- dimensions of ferriprehnite are longer than those of prehnite due to Fe substitution for Al at the M site."
},
"publisher": {
"en": "Japan Association of Mineralogical Sciences"
},
"publication_date": "2021",
"publication_name": {
"en": "Journal of Mineralogical and Petrological Sciences"
},
"volume": "116",
"number": "3",
"starting_page": "129",
"ending_page": "139",
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"eng"
],
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"doi": [
"10.2465/jmps.210127"
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"paper_title": {
"en": "The structural state of Finnish Cr- and V-bearing clinozoisite: insights from Raman spectroscopy"
},
"authors": {
"en": [
{
"name": "Mariko Nagashima"
},
{
"name": "Thomas Armbruster"
},
{
"name": "Daisuke Nishio-Hamane"
},
{
"name": "Boriana Mihailova"
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"description": {
"en": "Severe structural damage in Cr- and V-bearing clinozoisite (Czo) from the Outokumpu copper mine, Finland, was discovered by Nagashima et al. (Eur J Miner 23:731-743, 2011). Single-crystal X-ray and electron diffraction patterns indicated moderate-to-very-poor structural coherency, suggesting a high density of faults in the translational symmetry. However, the poor crystallinity cannot be attributed to self-radiation due to negligible concentrations of radioactive elements. Annealing of Cr- and V-bearing Czo up to 750 degrees C only slightly improved crystallinity. To solve this enigma, polarized Raman spectroscopy was applied to gain further insights into the structural state of the Cr+V-bearing Finnish Czo. According to the parallel-polarized Raman spectra of Cr+V-rich (Czo-ts3), Cr+V-bearing (Czo-ts2), and Cr+V-free (Czo-ts1) Czo, the peaks broaden with the Cr+V content, indicating increasing density of structural defects. Spectra from a euhedral Cr+V-bearing Czo single-crystal evidence intact structural domains by strong polarization and orientation dependence. Thus, the structural state of Finnish Czo should be described in terms of defect-rich segmented domains with common crystallographic orientation. The incorporation of V and Cr into the clinozoisite structure strongly affects the Raman-active O-H bond stretching modes near 3343 cm(-1) [(OH)a] and 3435 cm(-1) [(OH)b], assigned to O10-H...O4 and O10-H...O2 hydrogen bridges, respectively. The H...O2 hydrogen bonding is strongly promoted when M3 is partially occupied by Cr+V, and as a result, the linkages between the M2O(6)- and (M1, M3)O-6-chains are disturbed, leading to periodicity faults and size reduction of coherent structural domains. In the case of Fe-M3(3+) substitution for Al-M3, the local stress imposed by the larger M3-site cation is relaxed within the distorted M3O(6) octahedron. In the case of V-M3(3+) or Cr-M3(3+) substitution for Al-M3, M3O(6) octahedra are less distorted and local stress fields propagate farther than only to the first coordination sphere, thus disturbing the transitional symmetry. New high-resolution transmission electron microscopy (HRTEM) images indeed display nanocrystals of ca. 10 nm with common crystallographic orientation surrounded by amorphous regions. It is suggested that the segmentation of large coherent crystalline areas in Cr+V-rich Czo to nanocrystals may be triggered by a potential miscibility gap in combination with the sluggish diffusion behavior of Cr3+. Moreover, this study implies that nanostructures as commonly observed for metamict materials may also be caused by strain effects and/or exsolution phenomena precluded by tardy diffusion."
},
"publisher": {
"en": "Springer Science and Business Media LLC"
},
"publication_date": "2021-01",
"publication_name": {
"en": "Physics and Chemistry of Minerals"
},
"volume": "48",
"number": "1",
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"eng"
],
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"10.1007/s00269-020-01129-z"
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"paper_title": {
"en": "Multi-methodical study of the Ti, Fe2+ and Fe3+ distribution in chevkinite-subgroup minerals: X-ray diffraction, neutron diffraction, 57Fe Mössbauer spectroscopy and electron-microprobe analyses"
},
"authors": {
"en": [
{
"name": "Mariko Nagashima"
},
{
"name": "Thomas Armbruster"
},
{
"name": "Masahide Akasaka"
},
{
"name": "Asami Sano-Furukawa"
},
{
"name": "Daisuke Nishio-Hamane"
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{
"name": "Anna Malsy"
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"name": "Teruyoshi Imaoka"
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"name": "Kazuo Nakashima"
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"en": "© 2020, Springer-Verlag GmbH Germany, part of Springer Nature. Three non-metamict chevkinite-subgroup minerals, space group P21/a, from Cape Ashizuri, Japan, (No. 1), Tangir Valley, Diamar District, Pakistan (No. 2) and Haramosh Mts., Skardu district, Pakistan, (No. 3) were studied by crystal chemical techniques. Powder X-ray diffraction and transmission electron microscopic observations confirmed well crystalline samples. Electron-microprobe analyses indicated the general composition [(REE, Ca)4Fe2+(Fe2+, Fe3+, Ti)2Ti2(Si2O7)2O8] known for chevkinite-(Ce). Site scattering values determined by single-crystal X-ray structure refinements suggested assignment of subordinate Nb to the octahedral M3 and M4 sites, minor Th to M1 for the Ashizuri sample and minor Mg to M1 for both samples from Pakistan. Neutron time-of-flight powder diffraction studies were applied to determine the Ti/Fe distribution among octahedral sites for all samples and Mössbauer spectroscopy served for the Fe valence assignment at the four octahedral sites. Combined results gave the simplified formulas with Ce as dominant REE: No. 1 A(REE,Ca)4M1(Fe2+,Ti)M2(Ti,Fe3+)2M3,M4(Ti,Fe2+,Nb)2(Si2O7)2O8, No. 2 A(REE,Ca)4M1(Fe2+,Fe3+,Mg)M2(Ti,Fe3+)2M3,M4(Ti,Fe2+)2(Si2O7)2O8 and No. 3 A(REE,Ca)4M1(Fe3+,Fe2+,Mg,Ti)M2(Ti,Fe3+)2M3,M4(Ti,Fe2+)2(Si2O7)2O8. The dominant iron valence at M1 of the Haramosh sample (No. 3) is ferric whereas for samples Nos. 1 and 2 iron is ferrous. The structure of chevkinite-subgroup minerals consists of octahedral layers (M2, M3 and M4) alternating with an intermediate layer containing disilicate groups, REE polyhedra and strongly distorted M1 octahedra. Increased O atomic displacement parameters within the intermediate layers indicate disorder and/or strain to fit the extension of the embracing octahedral layers. A statistical analysis of chevkinite-subgroup structures (space groups P21/a, C2/m and P21/m) indicates a positive correlation between < M1–O > bond length and M1 bond angle variance. A negative correlation is found between < M1–O > bond length and the disilicate bending angle Si–O–Si, varying between ca. 160° and 175°. Outliers of this trend are delhuyarite-(Ce) Ce4Mg(Fe3+2W)□(Si2O7)2O6(OH)2, mainly due to octahedral W6+ and vacancies in the octahedral layers associated with OH groups, and synthetic Nd end-members with strong bonds between Nd and the intersecting O of the disilicate group. The observed trends reflect the main mechanisms in the intermediate layer to adopt to the size of the embracing rigid octahedral layers formed by M2, M3 and M4 octahedra."
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"publisher": {
"en": "Springer Science and Business Media LLC"
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"publication_date": "2020-06",
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"en": "Physics and Chemistry of Minerals"
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"paper_title": {
"en": "Aluminosugilite, KNa2Al2Li3Si12O30, an Al analogue of sugilite, from the Cerchiara mine, Liguria, Italy"
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"authors": {
"en": [
{
"name": "Mariko Nagashima"
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{
"name": "Chihiro Fukuda"
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{
"name": "Takashi Matsumoto"
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{
"name": "Teruyoshi Imaoka"
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"en": "Abstract. Aluminosugilite (IMA2018-142), ideal formula\nKNa2Al2Li3Si12O30, is a new mineral that was found\nin the interstices in manganiferous metacherts from the Cerchiara mine,\nLiguria, Italy. Aluminosugilite is an Al analogue of sugilite belonging to\nthe milarite group. It occurs as aggregates of small prismatic and/or\ngranular crystals up to 1 mm in length, and it is pinkish-purple with a pale purple\nto white streak and a vitreous lustre. It has a Mohs hardness of 6–6.5. Its\ncleavage is indistinct, poor on (0001).\nMeasured and calculated densities are Dmeas.=2.71–2.72 g cm−3\nand Dcalc.=2.73 g cm−3, respectively. Aluminosugilite is\noptically uniaxial (–), with ω=1.577–1.586 and ε=1.575–1.585, with a weak pleochroism. The magnetic susceptibility is\nlower than that for sugilite. Aluminosugilite is insoluble in HCl, HNO3\nand H2SO4, like sugilite. The empirical formula of aluminosugilite\ncalculated on the basis of O =30 from the result obtained by\nelectron microprobe analysis and laser-induced breakdown spectroscopy is\nK0.99Na1.99(Al1.38Mn0.313+Fe0.243+Ti0.05Mg0.01)Σ1.99Li3.06Si11.99O30. Structure refinement converged to\nR1=2.17 %. Its space group is hexagonal P6∕mcc, with unit-cell\nparameters a=9.9830(4) Å, c=13.9667(5) Å and V=1205.45(7) Å3. Based on the refined site occupancies, the ideal structural\nformula of aluminosugilite is\nCKBNa2AAl2T2Li3T1Si12O30.\nThe variation of the A–O3 distance is governed by the cationic substitution\nat the A site. The a and c dimensions of aluminosugilite are shorter than\nthose of sugilite due to Al substitution for Fe3+ at the A site."
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"en": "European Journal of Mineralogy"
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"en": "Crystal chemistry of Sr–rich piemontite from manganese ore deposit of the Tone mine, Nishisonogi Peninsula, Nagasaki, southwest Japan"
},
"authors": {
"en": [
{
"name": "Mariko NAGASHIMA"
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{
"name": "Yuko SANO"
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{
"name": "Takako KOCHI"
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{
"name": "Masahide AKASAKA"
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"name": "Asami SANO–FURUKAWA"
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"en": "Japan Association of Mineralogical Sciences"
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"paper_title": {
"ja": "Distribution of Cr3+ between octahedral and tetrahedral sites in synthetic blue and green (CaMgSi2O6)95(CaCrAlSiO6)5-diopsides.",
"en": "Distribution of Cr3+ between octahedral and tetrahedral sites in synthetic blue and green (CaMgSi2O6)95(CaCrAlSiO6)5-diopsides."
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"authors": {
"ja": [
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"name": "Akasaka, M"
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"name": "Takasu, Y"
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"name": "Handa, M"
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"ja": "三重県伊勢産新鉱物ランタンフェリ赤坂石およびランタンフェリアンドロス石"
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{
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"en": "Crystal structure of Vanadoallanite-(La) : a new epidote-group mineral"
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"ja": "放射性元素に起因しない結晶性の低下現象は,普遍的であるにもかかわらず,発生範囲が限定的で光学顕微鏡下で観察できず,さらに長周期原子配列やナノスケールでの補足が困難なため見過ごされてきたと考えられる。\n基課題では研究代表者が天然緑簾石族鉱物から発見した本現象に関して,海外共同研究者の協力のもと,偏光顕微ラマン分光スペクトルを検討した結果,本現象は「原子配列の周期性に乱れがない同方位を持つ結晶子が断片化し,それらの境界領域の結晶性が低下している状態」であると明らかになった。さらに検討結果に基づき,その原因と発生メカニズムに関して仮説を提唱するに至った(Nagashima et al.2021)。\nCOVID-19の流行により,海外への渡航を当初の予定から延期せざる得ない状況となったため,海外共同研究者と今後の方策についてメールやオンラインで議論を重ねたところ,上述の現象の原因と発生メカニズムを解明するために,組成の異なる緑簾石族鉱物から偏光ラマン分光スペクトルを取得し,本鉱物の結晶構造内の原子結合状態と元素分布の関係を明らかにすることが重要であるという共通認識が得られた。これに基づき,事前準備として鉱物結晶25試料を選定し,それらの観察および化学分析を実施した。\nさらに基課題で提唱した仮説の検証に適した合成物質を得るためにピストンシリンダー型高圧発生装置で実験を行った。合成生成物を検討した結果,化学組成に基づき対象とする物質が合成されたことが確認され,それらは偏光ラマンスペクトルを取得可能な粒子サイズであった。"
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"ja": "フィンランド産クリノゾイサイト(緑簾石族鉱物)の研究で発見した放射性元素に起因しない結晶性の低下(Nagashima et al. 2011)は,結晶質物質の新しい非晶質化作用の存在を示唆するが,その原因やメカニズムは未解明である.本申請課題は「放射性元素に起因しない原子配列の乱れを引き起こす原因は?」という問いに対する答えを詳細な観察や精密な解析で把握した実態に基づいて見出すことを目的に進めている。\n平成30年度は,主にラマン分光法を用いた短周期原子配列の評価を実施した。評価に用いた試料は次の4つに分類される; 1)フィンランド産含Cr+Vクリノゾイサイト,2)合成Al-V3+系クリノゾイサイト(= mukhinite), 3)天然Al-Fe3+系緑簾石(4試料), 4)放射性元素によりメタミクト化した褐簾石(2試料)。\nまた,mukhinite(試料2)の合成実験結果および生成物を用いた結晶化学的研究を国際誌に公表し,これまで未解明であった緑簾石族鉱物中のV3+の挙動や結晶構造への影響を明らかにした(Nagashima et al. 2019)。なお,これはmukhiniteの世界初の合成例である。X線単結晶構造解析を用いた結晶化学的検討の結果,長周期原子配列という観点から合成mukhiniteは結晶質と結論されるが,本プロジェクトで得られた同試料のラマンスペクトルの詳細な解析で,既知の緑簾石鉱物では観察されない半値幅の大きなピークが100 cm-1付近に出現し,さらにO-H stretching modeにおいても既知のO10-H…O4結合に属さないピークが複数みられることが確認された。これらの事実は,格子欠陥や原子配列の周期性の低下などの短周期配列の乱れの存在を示しており,フィンランド産クリノゾイサイトにも含まれるバナジウムに起因すると考えられる。",
"en": "Severe structural damage which is not attributed to self-radiation due to radioactive elements was observed in natural Cr+V-bearing clinozoisite. To investigate this phenomenon polarized Raman spectroscopy was applied in this study. This phenomenon is understood as \"the fragmentation of the crystalline matter preserving the original atomic arrangement into crystalline nano regions with the non-crystalline boundary\". The cause of this phenomenon is that the orientational disorder of the OH group is strongly promoted when the M3 octahedron is partially occupied by V(+Cr), and as a result, the linkages between the structural units are disturbed, leading to the periodicity fault and size reduction of coherent structural domains."
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"ja": "本研究では,(1) 95 Ma以降のイグニンブライト・フレアーアップ形成をもたらしたテクトニクスと大規模珪長質マグマの起源物質について考察し,西中国白亜紀カルデラ群形成のテクトニック・岩石学的モデルを提案すること,さらに(2) 活発な部分溶融によって形成された苦鉄質マグマは,下部地殻にアンダー・プレーティングするとともに,アンダー・プレーティングした苦鉄質岩や地殻下部に存在した付加体起源の堆積岩・苦鉄質岩を大量に溶融させ,多量の珪長質マグマが形成されイグニンブライト・フレアーアップの原因となったとする新たなモデルを提案することである.\nまず,大規模珪長質火成岩類のU-Pbジルコン年代を明らかにしたことで,イグニンブライト・フレアーアップの期間が99-86Maと明確となった.また,カルデラ群分布域に広く分布する防府バソリスの年代についても検討したところ,96―88 Maの年代が得られた.さらに,カルデラ群分布地域に重複して分布する斑れい岩や閃緑岩のK-Ar年代も測定した結果,これらの年代は100-85Maで,大規模珪長質マグマの活動と同時にマントル由来の苦鉄質マグマの活動も同時進行していたことが明らかになった.\n珪長質マグマの活動は,南は中央構造線から北は山陰海岸に及ぶことから,西中国白亜紀カルデラ群形成のテクトニクスとしては,フラットな沈み込みが想定される.今後は同位体比の研究も踏まえながら,西中国白亜紀カルデラ群形成のテクトニック・岩石学的モデルを構築していきたい.",
"en": "In the Nagato area, Yamaguchi Prefecture, we found a Cretaceous caldera named the Nagato-Hohoku caldera, which is similar with graben caldera. The caldera shows an elongated shape in the E-W direction, and bends to the NNE at the eastern part, occurring within >34 km E-W by >14 km N-S.\nAs to the murakamiite, 1) the element partitioning of murakamiite during metasomatism to form albitite took place under a strong control of crystal structure, 2) Li isotopic values should have resulted from hydrothermal fluid-rock interactions at the temperatures of 300-600°C (hydrothermal stage), and 3) intra-crystalline Li isotope diffusion, or involvement of deep-seated, Li-Na-enriched subduction-zone fluids with low Li isotopic values, were discussed. Lead isotopic ratios of the Cretaceous lead ores of Yamaguchi Prefecture, Japan, especially those of the Akiyoshi Plateau were measured. The genetic relationships of Naganobori mine and the Hanano-yama pluton were examined as a case study."
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"research_project_title": {
"ja": "ケイ線石のFe固溶度による地質温度計・酸素分圧計",
"en": "Fe-in-sillimanite thermometer and oxygen-borometer"
},
"investigators": {
"en": [
{
"name": "Kawasaki Toshisuke"
}
],
"ja": [
{
"name": "川嵜 智佑"
},
{
"name": "永嶌 真理子"
},
{
"name": "齊藤 哲"
}
]
},
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"ja": "日本学術振興会",
"en": "Japan Society for the Promotion of Science"
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"en": "Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)"
},
"category": {
"ja": "基盤研究(C)",
"en": "Grant-in-Aid for Scientific Research (C)"
},
"institution_name": {
"ja": "愛媛大学",
"en": "Ehime University"
},
"from_date": "2017-04-01",
"to_date": "2020-03-31",
"overall_grant_amount": {
"total_cost": "4420000",
"direct_cost": "3400000",
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"description": {
"ja": "超高温変成作用の温度圧力条件での相平衡再現実験からケイ線石へのFe固溶量を調べている過程で,平成29年度に,9キロバール,1050 ℃でケイ線石+Fe2O3およびケイ線石+Fe3O4からFeAlO3相が晶出していることを見出したので,平成30年度は,反応性を促進させる目的で1ミクロン以下に粉砕した出発物質を用いた実験を試みた.しかしながら,得られた実験生成物は結晶成長が悪く,粒径1ミクロン程度までにしか成長していなかった.それ故,極細微粒出発物質を用いた再現実験を実施することは断念した.これまで実施してきたケイ線石とFe酸化物を用いた再現実験で得られた生成物を詳細に再検討した.その結果,含水条件のもとで,部分溶融した生成物には,Fe酸化物が消滅してFeAlO3相が結晶化していたことが判明した.部分溶融を経ていない生成物には,FeAlO3相は結晶化しておらず,Fe酸化物+ケイ線石+コランダムが再結晶化していた.Fe2O3と共存するケイ線石中のFe固溶量がFe3O4と共存する場合よりも大きいことが明らかになった.このことに加えて,FeAlO3相と共存するケイ線石中のFe固溶量も調べることにした.そのためにFeAlO3相を大気中で合成することを試みた.これらの研究成果は,日本鉱物科学会2018年総会,The Ninth Symposium on Polar Science,第95回西日本東南極研究セミナー,第18回日本地質学会四国支部総会,変成岩などシンポジウム2019で公表した.また,FeAlO3相が結晶化した高温高圧再現実験について,現在投稿準備中である.",
"en": "In order to establish the new geothormoborometer for ultrahigh-temperature metamorphic rocks, high-pressure and high-temperature experiments were carried out at pressures 5 to 15 kbar and temperatures 800 to 1300 C on the Fe solubility in sillimanite. The thermodynamic model was proposed for the Fe partitioning among sillimanite and iron-oxides. I found FeAlO3 phase in the run products partially melted under hydrous condition. The phase contains fairly amount of FeTiO3 component indicating the solid solution formation with ilmenite. The FeAlO3 phase would be a new index mineral for ultrahigh-temperature metamorphism."
},
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"ja": "アジア大陸東縁における白亜紀火成活動と水平沈み込みからロールバックへの変換過程",
"en": "Changing processes from flat-slab subduction to slab roll-back from Jurassic to Cretaceous at the eastern margin of Asian continents"
},
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"en": [
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"name": "Imaoka Teruyoshi"
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{
"name": "ITAYA Tetsumaru"
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{
"name": "KAMEI Atsushi"
}
],
"ja": [
{
"name": "今岡 照喜"
},
{
"name": "君波 和雄"
},
{
"name": "永嶌 真理子"
},
{
"name": "板谷 徹丸"
},
{
"name": "亀井 淳志"
}
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},
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"en": "Japan Society for the Promotion of Science"
},
"system_name": {
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"en": "Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (C)"
},
"category": {
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"en": "Grant-in-Aid for Scientific Research (C)"
},
"institution_name": {
"ja": "山口大学",
"en": "Yamaguchi University"
},
"from_date": "2015-04-01",
"to_date": "2018-03-31",
"overall_grant_amount": {
"total_cost": "4680000",
"direct_cost": "3600000",
"indirect_cost": "1080000"
},
"description": {
"ja": "近年,アジア大陸東縁におけるジュラ紀から白亜紀のスラブの水平沈み込みとそれに続くロールバックといったテクトニクス変化が提案されている。この研究においては,スラブのロールバック過程に対応した西南日本の諸イベントについて解明した。とくに105 Maの京都ランプロファイアーの高Nb玄武岩マグマのマグマ成因論,大和鉱山の鉱床形成に関連した於福プルトンの岩石成因論,山口県蓋井島のマグマ混合・混交現象,愛媛県岩城島の交代作用岩からの新鉱物「村上石」の発見が特筆される。",
"en": "Recently, flat-slab subduction to slab roll-back processes from Jurassic to Cretaceous at the eastern margin of Asian continents were proposed. Several geological events, and magma and mineral genesis related to slab roll-back process were revealed in this study; magma genesis of the High-Nb basalt of the Kyoto lamprophyres, petrogenesis of the Cretaceous Ofuku pluton related to the ore-genesis of the Yamato mine, magma mixing and mingling in the Futaoi-island, Yamaguchi Prefectute, and finding a new mineral “Murakamiite” in metasomatites from the Iwagi Islet, Ehime Prefecture, Japan."
},
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"en": "High-pressure and high-temperature experiments of phase equilibria on armalcolite for the detailed analysis of P-T path of ultrahigh-temperature granulites"
},
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"en": [
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"name": "Kawasaki Toshisuke"
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"ja": [
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"name": "川嵜 智佑"
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{
"name": "大和田 正明"
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{
"name": "志村 俊昭"
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{
"name": "永嶌 真理子"
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{
"name": "齊藤 哲"
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"description": {
"ja": "超高温変成作用の温度圧力条件(6~12 kbar, 900~1100℃),logPO2=-10~-11の酸素分圧で,Feに富むアーマルコライトが安定な温度圧力条件を調べた.TiO2-FeO-MgO系において,総化学組成が0.15山口大学"
},
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},
"overall_grant_amount": {
"total_cost": "5070000",
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"description": {
"ja": "ヘグボマイト類はスピネルに似た、特殊な含水酸化鉱物である。ヘグボマイト類は最近様々な地域から報告されつつある。その変成度はホルンフェルスから超高温変成岩まで広範囲に及ぶ。しかしながら、ヘグボマイト類が人工的に合成されたことはなく、その安定領域や熱力学的性質は不明のままである。\n本研究において、山口大学のピストンシリンダー型高温高圧実験装置を用い、高温高圧実験をおこなった。750MPa、850℃の実験では、マグネシオヘグボマイト2N4Sの種結晶が消滅した。一方、750MPa、825℃の実験においてヘグボマイトの形成が確認された。これは世界初のヘグボマイト合成の成功である。",
"en": "Hogbomite-group minerals are complex hydrous oxides related to the spinel group. Reentry, hogbomite-group minerals have been reported from many localities. Their metamorphic grade covers a wide range, from hornfels to UHT metamorphic rocks. However, nobody has made synthetic hogbomite yet. Therefore, thermodynamic properties of hogbomite group minerals are unknown.\nThe experiments were carried out by piston-cylinder device at the Yamaguchi University. Seed crystals of magnesiohogbomite-2N4S are disappeared at above 750MPa and 850C. In contrast, hogbomite new crystals are produced at the condition of 750MPa and 825C. This is the world’s first success to make synthetic hogbomite."
},
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"ja": "含水鉱物中の水の固定機構-遷移元素の酸化数,席選択性と水素結合システムの関係",
"en": "Fixation mechanism of water in hydrous rock-forming mineral-Relation among oxidation state of the transition elements, cation distribution, and hydrogen-bonding system"
},
"investigators": {
"en": [
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"name": "NAGASHIMA Mariko"
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"ja": [
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"name": "永嶌 真理子"
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"ja": "総額: 3120千円 (直接経費: 2400千円, 間接経費: 720千円)"
},
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"description": {
"ja": "本研究では,低温変成作用および熱水作用によって生成する含水鉱物における遷移金属イオンの酸化数,結晶内分布と水素結合の関係の解明,およびそれらの鉱物における結晶構造と水素固定機構の解明を目指し,多角的な検討を行った.その結果, 1)陽イオン置換が結晶構造に与える影響は,置換しあうイオンの大きさによるだけではなく,同じ配位数の配位席であっても配位席がおかれた幾何学的環境に依存することの解明, 2)パンペリー石と類縁鉱物,および緑簾石の結晶構造の幾何学的関係に関するイオン置換と配位多面体の構造的変化の類似性と相違性という観点からの体系的解明, 3)遷移元素の酸化数変化と水素結合システムの関係の解明, 4)緑簾石族鉱物における放射性元素に起因しない結晶度の低下という新現象の発見,を行った.",
"en": "Multi-approach to understand the relationship among the oxidation state of the transition elements, cation distribution, and hydrogen-bonding system in hydrous mineral formed by low-grade metamorphism and hydrothermal activity was carried out in this study. As the results of this study, I revealed as follows ; 1) the influence of cation substitution at octahedral sites was not only derived from ionic radius but also topological environment of octahedra, 2) The similarity and difference of pumpellyite and their related minerals, and epidote were systematically understood to focus on the cation substitution and the topology of polyhedra, 3) Relation between the oxidation state of transition elements and hydrogen-bonding system was well investigated, 4) the low-crystallinity of natural clinozoisite, which is not derived from radioactive elements, was newly discovered."
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"description": {
"ja": "山口大学大学院創成科学研究科の永嶌真理子若手先進教授,今岡照喜名誉教授、加納隆名誉教授、海洋研究開発機構の木村純一上席技術研究員、常青(Qing Chang)技術主任、株式会社リガクの松本崇博士らの共同研究グループは、リチウムを含む新鉱物を愛媛県上島町岩城島から発見しました。\n 新鉱物は2022年6月2日付で国際鉱物学連合 (International Mineralogical Association)の新鉱物・命名・分類委員会 (Commission on New Minerals, Nomenclature and Classification)により新種として承認され,「Ferro-ferri-holmquistite」(フェロフェリホルムキスト閃石)と命名されました。"
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"ja": "プレスリリース:リチウムを含む新鉱物を発見!「アルミノ杉石」と命名!!"
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"ja": "<概要> 創成科学研究科地球科学分野の永嶌真理子准教授,株式会社Rigakuの松本 崇博士,ジェムリサーチジャパン株式会社の福田千紘氏,今岡照喜名誉教授,イタリアAssociazione Micro-mineralogica Italiana のGianluca Odicino氏,Gianluca Armellino氏 のグループがイタリアのCerchiara鉱山から新鉱物を発見しました。国際鉱物学連合(International Mineralogical Association)の新鉱物・命名・分類委員会(Commission on New Minerals, Nomenclature and Classification)の審査によって新鉱物であることが4月8日に正式に承認され「アルミノ杉石」(IMA No. 2018-142)と命名されました。"
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"ja": "プレスリリース:リチウムを含む新鉱物を発見!「村上石」と命名!!"
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"ja": "【概要】 山口大学大学院創成科学研究科の今岡照喜教授、永嶌真理子准教授、加納隆名誉教授、海洋研究開発機構の木村純一上席技術研究員、常青(Qing Chang) 技術主任、ジェムリサーチジャパン株式会社の福田千紘課長らの共同研究グループは、リチウムを含む新鉱物を愛媛県上島町岩城島で発見しました。発見された鉱物は著名な鉱物学者・岩石学者でもある村上允英(山口大学名誉教授)にちなみ「村上石」と命名されました。\nこれは国際鉱物学連合 (International Mineralogical Association)*1の新鉱物・命名・分類委員会(Commission on New Minerals、 Nomenclature and Classification)*2により新種として2016年10月7日に承認され、11月29日にイギリスの学術雑誌「Mineralogical Magazine」のNew Mineralsリストに掲載されました。\n「村上石」はLiCa2Si3O8(OH)という化学式で表されるリチウムを多量に含む珍しい鉱物です。そして本鉱物が属するペクトライトグループには、このような組成を持つ鉱物が存在するに違いないと世界中の鉱物学者が予測しておりましたが、長らく空位のままでした。今回の「村上石」の発見は、このミッシングピースを埋める成果であり、大変貴重な発見といえます。"
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"ja": "プレスリリース:レアアースを主成分に持つ二種類の新鉱物を発見"
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"ja": "<概要> 山口大学大学院理工学研究科の永嶌真理子准教授,東京大学物性研究所の浜根大輔技術職員,愛媛大学大学院理工学研究科の皆川鉄雄教授と冨田宣光(博士前期課程),稲葉幸郎(鉱物研究家)らのグループが共同で,レアアースのランタンを主成分に持つ二種類の新鉱物を三重県伊勢市矢持町の山中から発見しました。発見された新鉱物は「ランタンフェリ赤坂石 / Ferriakasakaite-(La)」と「ランタンフェリアンドロス石 / Ferriandrosite-(La)」で,前者は著名な鉱物学者である赤坂正秀(島根大学教授)にちなみ命名されました。これらは国際鉱物学連合(International Mineralogical Association)*1の新鉱物・命名・分類委員会(Commission on New Minerals, Nomenclature and Classification)*2により新種として2014年2月3日に承認されました。"
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"ja": "プレスリリース:レアアースを含む新種の鉱物「Vanadoallanite-(La)」を発見"
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"ja": "<概要> 山口大学大学院理工学研究科の永嶌真理子准教授,東京大学物性研究所の浜根大輔博士,愛媛大学理学研究科の皆川鉄雄教授と冨田宣光(博士前期課程),稲葉幸郎(鉱物研究家)らのグループが共同で,レアアースのランタン(La)を含む褐簾石(かつれんせき)の新種「ランタンバナジウム褐簾石 / Vanadoallanite-(La)」を三重県伊勢市矢持町の山中から発見し,国際鉱物学連合(International Mineralogical Association: IMA)*1の新鉱物・命名・分類委員会(Commission on New Minerals, Nomenclature and Classification: CNMNC)*2により新鉱物として2013年3月1日に承認されました。"
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"ja": "An Introduction to Rock-Forming Minerals 3rd Edition"
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"ja": "岩石・鉱物分野で世界的に最も有名な教科書である\"An Introduction to the Rock-Forming Minerals\"の3rd edition出版にあたり,イギリス地質学会と著者からの依頼に基づき,原稿の内容確認や修正などに無償で協力した。その功績により協力者の一人としてPreface to Third Editionに日本人の地球科学関係者で唯一名前が明記された。"
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